Evaluation of physical and chemical characteristics of wastewater and sludge of Zahedan urban wastewater treatment plant for reuse.

Following the water shortage in the world, the use of wastewater as a sustainable resource has been considered in large volume. The study conducted to evaluate the physical and chemical characteristics of the wastewater and sludge of the Zahedan urban wastewater treatment plant showed that the wastewater and sludge treatment system of the treatment plant has high efficiency and effectiveness in removing the investigated parameters. The investigated parameters in the effluent included Chemical oxygen demand (COD), Biochemical oxygen demand (BOD), and Total suspended solids (TSS), turbidity, temperature, nitrate, nitrite, phosphate, pH, zinc, cobalt, lead and copper. Also, the investigated parameters in the sludge included Mixed liquor suspended solids (MLSS), Mixed liquor volatile suspended solids (MLVSS), pH, electrical conductivity and heavy metals. The results showed that the average concentration of metals in the treated effluent is Zn > Mn > Cu > Pb > Ni > Cr > Cd ،and Chemical oxygen demand and Biochemical oxygen demand in the effluent of this treatment plant are on average 171 and 44.4 mg/L, respectively, and its discharge in surface water is limited, but it can be applied for agriculture. Also, the purified sludge had the necessary standards and could be used as soil or household fertilizer and compost for agricultural land.

Degradation of reactive red 198 dye from aqueous solutions by combined technology advanced sonofenton with zero valent iron: Characteristics/ effect of parameters/kinetic studies.

Dyes are one of the most common contaminants in industrial effluents, whose continuous release into the environment has become an increasing global concern. In this work, nanoparticles of zero-valent iron (NZVI) were synthesized using the chemical regeneration method ،and were utilized for the first time as a catalyst in the advanced Sono-Nano-Fenton hybrid method for the decomposition of Reactive Red 198 (RR198). The properties of zero-valent iron nanoparticles were analyzed using SEM and XRD. The effect of pH, initial dye concentration, nanoparticle dosage, zero-valent iron and H2O2 concentration on the decomposition efficiency of Red Reactive 198 was investigated. Comparing the efficiency of Reactivate 198 dye degradation in Sonolysis, Sono-NZVI, Sono-H2O2 and Sono-Nano Fenton processes showed that 97 % efficiency was achieved by the Sono-Nano Fenton process in 60 min. The kinetics of the removal process showed that this process follows pseudo-first-order kinetics and the Langmuir-Hinshelwood model. The results indicate that the effectiveness of the ultrasonic process in removing resistant organic pollutants such as dyes increases tremendously with the synergy of the Fenton process.

The utility of ultraviolet beam in advanced oxidation-reduction processes: a review on the mechanism of processes and possible production free radicals.

Advanced oxidation processes (AOPs) and advanced reduction processes (ARPs) are a set of chemical treatment procedures designed to eliminate organic (sometimes inorganic) contamination in water and wastewater by producing free reactive radicals (FRR). UV irradiation is one of the factors that are effectively used in oxidation-reduction processes. Not only does the UV beam cause the photolysis of contamination, but it also leads to the product of FRR by affecting oxidants-reductant, and the pollutant decomposition occurs by FRR. UV rays produce active radical species indirectly in an advanced redox process by affecting an oxidant (O3, H2O2), persulfate (PS), or reducer (dithionite, sulfite, sulfide, iodide, ferrous). Produced FRR with high redox potential (including oxidized or reduced radicals) causes detoxification and degradation of target contaminants by attacking them. In this review, it was found that ultraviolet radiation is one of the important and practical parameters in redox processes, which can be used to control a wide range of impurities.

A review of novel methods for Diuron removal from aqueous environments.

Runoff from intensive agriculture, which contains many sources of pollutants, including herbicides, for instance, Diuron, has threatened the environment and human health. The intrusion of these toxins into water sources poses a serious challenge to human society, and the rising release of these toxins has always been of concern to water researchers. The consequences of the release of these toxins into water sources are destructive and debilitating to human life. Today, the contamination of surface water and wastewater by pesticide residues, especially from agricultural activities and pesticide factories, has grown significantly. One of the pesticides commonly applied around the world is Diuron. There are various techniques for removing Diuron, the most important of which are adsorption and advanced oxidation. This review presents the characteristics, mechanisms, and emerging methods of removing Diuron. The use of absorbents, such as sludge-derived modified biochar (SDMBC600) and bottom ash waste (BAW-200), is discussed in detail. Additionally, the main features, benefits, and limitations of new technologies like hydrodynamic cavitation are enumerated. The effectiveness of novel adsorbents in Diuron removal is also discussed.

Health risk assessment of BTEX compounds (benzene, toluene, ethylbenzene and xylene) in different indoor air using Monte Carlo simulation in zahedan city, Iran.

The presence of benzene, toluene, ethylbenzene, and xylene compounds (BTEX) in the breathing air outside and inside buildings is one of the most significant problems related to human health today. This study was performed to determine the concentration of BTEX pollutants in indoor environments. PhoCheck was used to detect the concentration of BTEX compounds. In this study, the concentration (BTEX pollutant) was assessed in four indoor spaces, including restaurants, laundries, hair salons, and photocopying centers. The results showed that the average concentration of all four searched compounds was higher than the recommended limit of the Environmental Protection Agency (EPA). The results of carcinogenic risk assessment by benzene and ethylbenzene compounds show 2153 × 10-4 and 913 × 10-5 respectively. The HQ values for toluene and xylene were 1.397 and 0.505, respectively, indicating that exposure to toluene alone may have adverse effects on human health, while exposure to xylene alone has no adverse effects. The hazard index (HI) for toluene and xylene pollutants was higher than one. An HI value higher than one means that the two contaminants toluene and xylene in the air we breathe may have adverse effects on human health. As a result, the necessary control measures should be taken to prevent the unfavorable effects of these two pollutants.